In the first step, ammonia is converted to sodium amide: The sodium amide is subsequently combined with nitrous oxide: These reactions are the basis of the industrial route, which produced about 250 tons per year in 2004, with production increasing owing to the popularization of airbags.[5]. The azide anion is very similar in each form, being centrosymmetric with N–N distances of 1.18 Å. It possesses the NFPA 704's highest rating of 4 on the health scale. 1 Structures Expand this section. CopyCopied, InChI=1S/N3/c1-3-2/q-1 This should be considered when choosing a container for sodium azide solutions. Treatment of sodium azide with strong acids gives hydrazoic acid, which is also extremely toxic: Aqueous solutions contain minute amounts of hydrogen azide, the formation of which is described by the following equilibrium: Sodium azide can be destroyed by treatment with nitrous acid solution:[9]. The toxicity of this compound is comparable to that of soluble alkali cyanides. CopyCopied, CSID:30959, http://www.chemspider.com/Chemical-Structure.30959.html (accessed 06:23, Nov 13, 2020) 528-532 (, Last edited on 6 September 2020, at 15:28, National Institute for Occupational Safety and Health, "The crystal structures of lithium, sodium and strontium azides", "Studies of the Effect of Sodium Azide on Microbic Growth and Respiration: I.

In hospitals and laboratories, it is a biocide; it is especially important in bulk reagents and stock solutions which may otherwise support bacterial growth where the sodium azide acts as a bacteriostatic by inhibiting cytochrome oxidase in gram-negative bacteria; however, some gram-positive bacteria (streptococci, pneumococci, lactobacilli) are intrinsically resistant. Toxicity may also include hypotension,[20] blindness and hepatic necrosis. This can also create a dangerous situation when azide solutions are disposed down the drain into the sanitary sewer system. [5], Sodium azide is an ionic solid. Contents. Sodium azide is a white crystalline solid that is highly toxic when ingested or inhaled. The Na+ ion has octahedral geometry. It is used for the preparation of other azide compounds. ACMC-1BUCT. It is an ionic substance, is highly soluble in water, and is very acutely toxic. Molecular Formula: CsN 3: Synonyms: caesium azide. Molecular Weight: 174.926 g/mol. Sodium azide is a versatile precursor to other inorganic azide compounds, e.g., lead azide and silver azide, which are used in explosives. Determination of Azide in Aqueous Samples by Ion Chromatography with Suppressed Conductivity Detection. Molecular Formula: AgN 3: Synonyms: SILVER AZIDE. The sodium that is formed is a potential hazard alone and, in automobile airbags, it is converted by reaction with other ingredients, such as potassium nitrate and silica. Component Compounds : CID 33558 (Azide ion) CID 23954 (Silver) Dates: Modify . Newer-generation air bags contain nitroguanidine or similar less sensitive explosives. It is an ionic substance, is highly soluble in water, and is very acutely toxic. Structure, properties, spectra, suppliers and links for: Azide, 7782-79-8. [17] Even minute amounts can cause symptoms. This colorless salt is the gas-forming component in many car airbag systems. AKOS025294946. Azide is not formed directly from diatomic nitrogen and azide ions are terribly explosive. Component Compounds: CID 33558 (Azide ion) CID 5354618 (Cesium) Dates: Modify: 2020-09-05. Metal in the plumbing system will react, forming highly sensitive metal azide crystals which can accumulate over many years. 59, No.

[15], Sodium azide has caused deaths for decades. Silver azide (dry) [Forbidden] More... Molecular Weight: 149.889 g/mol. [11], It is used in agriculture for pest control of soil-borne pathogens such as Meloidogyne incognita or Helicotylenchus dihystera. Each azide is linked to six Na+ centers, with three Na-N bonds to each terminal nitrogen center.[7]. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite™, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite™, Compounds with the same molecular formula, Search Google for structures with same skeleton.

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