Environ. 10:R51. doi: 10.1016/j.micres.2015.11.007, Riabchenko, L., Podcherniaev, D., Kotlova, E., and Yanenko, A. J. Mol. J. Pest Manag. A complex containing equal quantities (by weight) of carboxylic acid and tri-substituted nitrogenous base is then charged to the reactor at a rate of 85.4 ml/hr. 17, 170–178. the oxidative cleavage of alkenes. doi: 10.1016/j.mib.2016.04.020, Swiderska, A., Berndtson, A. K., Cha, M. R., Li, L., Beaudoin, G. M., Zhu, J., et al. Microbiol. Res. doi: 10.1093/molbev/msy096, Kumar, V., Seth, A., Kumari, V., Kumar, V., and Bhalla, T. C. (2015). Biotechnol. The ammonia may be contacted with the raw material in the presence of an alumina or a silica gel catalyst. Appl. It is further theorized that the complex (Equation 1) is broken down when contacted with ammonia at the elevated reaction temperatures. doi: 10.1021/jm100762r, Gerasimova, T., Novikov, A., Osswald, S., and Yanenko, A. Extremophiles 2, 347–357. where δ indicates partial charge, the δ + and δ - denote partially developed charges rather than fully developed or formal charges, e.g., see Jack Hene, Physical Organic Chemistry, 2nd Ed., McGraw-Hill Book Co., Inc., (1962) p. 286. The role of bacteria in nutrient recycling in tropical mangrove and other coastal benthic ecosystems. Evol. The primers contained adapters for Illumina MiSeq sequencing (Ilumina, San Diego, CA, USA). b. contacting said single-phase reaction mixture with ammonia at a temperature of about 200° to about 800°C, c. recovering the nitriles thus produced, and. (2014). doi: 10.1007/BF00164456, Grogan, J., DeVito, S. C., Pearlman, R. S., and Korzekwa, K. R. (1992). The reaction preferably takes place in the presence of silica gel or alumina. doi: 10.1002/chem.201701497, Yilmaz, P., Parfrey, L. W., Yarza, P., Gerken, J., Pruesse, E., Quast, C., et al. The Supplementary Material for this article can be found online at: https://www.frontiersin.org/articles/10.3389/fenvs.2019.00103/full#supplementary-material, Abbas, Z., Akmal, M., Khan, K. S., and Fayyaz-ul-Hassan (2014). Sci., 03 July 2019 doi: 10.1016/0278-6915(88)90111-1, Wibberg, D., Luque-Almagro, V. M., Igeño, M. I., Bremges, A., Roldán, M. D., Merchán, F., et al. Appl. Nitriles are prepared from the corresponding carboxylic acids nitrogen base-carboxylic acid complex. A process according to claim 1 wherein said ammonia is contacted with said complex compound in the presence of a catalyst selected from the group consisting of silica gel and alumina. 1,046,015); and silica gel at 400°-500°C (Organic Synthesis, Vol. A Eur. b. contacting said complex with ammonia at a temperature of about 200° to about 800°C. A process for producing nitriles from corresponding carboxylic acid, said process comprising: a. forming a complex of said carboxylic acid and nitrogenous base comprising at least one compound selected from the group consisting of pyridine, alkyl derivatives of pyridine, quinoline, alkyl derivatives of quinoline, tri-substituted amines, and mixtures of the foregoing to form a single-phase reaction mixture.

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